不同产地及成熟度牛油果及其油脂品质比较

分析不同产地及成熟度牛油果及其油脂理化性质,脂肪酸组成及反式脂肪酸组成。结果表明:牛油果作为水果,粗脂肪含量和粗蛋白质含量很高;不同产地及成熟度牛油果溶剂提取所得油脂理化性质和脂肪酸组成有一定的差异。研究可为进一步开发牛油果油和制定牛油果油标准提供参考。     

Crude Oil Production

Current data on crude oil, field/lease condensate, and natural gas liquids produced from NGL plants. Updated on a monthly basis.     

橄榄油与椰子油混油基对类蛋黄酱乳液流变及冻融稳定性的影响

以类蛋黄酱体系为研究对象，运用Turbiscan、流变仪、粒度仪、显微镜研究在pH 3条件下橄榄油与椰子油不同比例复配（10∶ 0、9∶ 1、8∶ 2、7∶ 3）的混油基对于乳清分离蛋白-蛋黄卵磷脂稳定的乳液体系流变性质及冻融稳定性的影响。结果表明：随着椰子油比例增加，乳液黏度增加，弹性模量增加，橄榄油与椰子油质量比7∶ 3复配混油基制得的乳液具有最大的黏度和最高的弹性模量；所有乳液在4~40 ℃弹性模量下降，说明乳液在贮存、冷藏运输过程中内部结构完整，乳液具有良好的稳定性;蛋黄卵磷脂能够提高含椰子油（饱和脂肪酸含量高）乳液的冻融稳定性，并且椰子油比例越大（饱和程度越高），冻融稳定性提高效果越好;乳液冻融稳定性从高到低依次为橄榄油与椰子油质量比为7∶ 3>8∶ 2>9∶ 1>10∶ 0。     

Experimental determination of pesticide processing factors during extraction of seed oils

ABSTRACT

Processing Factors (PFs) reflect the concentration or dilution of pesticide residues resulting from food processing. PFs are key elements to demonstrate the compliance of processed foods with Maximum residue levels (MRLs) as set by Regulation 396/2005. While efforts have been made by the European Food Safety Authority (EFSA) and by national authorities to compile PFs from processing studies, such PFs are not available for all pesticides/processed product combinations. The EU vegetable oil and proteinmeal industry association (FEDIOL) has therefore developed a theoretical approach to approximate MRLs in crude vegetable oils and fats, based on the partition coefficient (log P_ow) of the pesticides and on the oil content of the raw materials. To substantiate this approach, a pilot-scale processing study was initiated with rapeseeds spiked with selected pesticides and the experimental PFs for these pesticides determined. The aims of this study were (i) to study the reliability of pilot-scale conditions for PF determination and (ii) to assess the experimental PFs obtained in comparison to the theoretical PFs proposed by FEDIOL. This study demonstrated that production yields obtained for crude oil and meal in this processing study are similar to those in industrial processes even if differences were observed in the individual production steps (mechanical or solvent extraction steps). The experimental PFs obtained confirmed that the chosen fat-soluble pesticides did concentrate in the oil fraction. For metalaxyl-M having a log P_ow lower than 3, a partitioning between the oil and the meal was observed, as expected. By comparing the experimental PFs and theoretical PFs, it can be concluded that the FEDIOL approach can be recommended as a suitable tool when PFs derived from specific processing studies are missing. Similar studies on pesticides with wider ranges of log P_ow are required in order to complete our conclusions on default PFs for vegetable oils.     

油介质下高速轮轨低黏着特性和撒砂试验研究

在车轮-钢轨高速滚动接触疲劳试验机上进行油介质下高速轮轨低黏着特性和增黏试验,研究油介质条件下不同速度、蠕滑率、轴质量以及撒砂对黏着系数的影响,最高试验线速度200 km/h。结果表明:黏着系数随蠕滑率的增加先增大、再微降随后趋于平稳,在蠕滑率3%左右达到最大;随着速度的增加,黏着系数呈快速下降趋势,如速度从50 km/h增加至200 km/h时,最大黏着系数从0.092下降至0.049;当轴质量由12 t增至16 t时,黏着系数仅略微增加了0.01;撒砂后,黏着系数约为未撒砂时的3倍左右,且依然随速度增加而降低;撒砂会使得试验后轮轨表面产生很多麻坑,从而增大了表面粗糙度,对增黏起到了一定作用,但增黏砂会对接触表面造成显著损伤,在极端条件下会促进滚动接触疲劳的萌生,威胁运行安全。     

Insights into pyrolysis and catalytic co-pyrolysis upgrading of biomass and waste rubber seed oil to promote the formation of aromatics hydrocarbon

To solve the problem of low aromatic hydrocarbon yield and selectivity in biomass catalytic pyrolysis, we used added oxygen-containing hydrogen supplier of rubber seed oil (RSO) with a higher hydrogen-to-carbon ratio to investigate the thermal decomposition behaviors, kinetic and production distribution of biomass, cellulose and RSO with the weight ratio of 1:2 using thermogravimetric analyzer (TGA) for kinetic analysis and fixed bed reactor with the feed composition of 1.2 g: 0.4 mL/min (Biomass to RSO) for product distribution in non-catalytic and catalytic co-pyrolysis over a HZSM-5 catalyst. The results show that there was a positive synergistic interaction between biomass and RSO according to the difference in weight loss, which could decrease the formation of solid coke at the end of experiment. The addition of the HZSM-5 catalyst can markedly increase the reaction activity, accelerate the reaction rate, and the reaction Ea, leading to a substantial increase in the conversion rate; furthermore, the residual carbon content will decrease, and the activations of Cellulose + RSO + Catalyst and Biomass + RSO + Catalyst are only 50.80 kJ/mol and 62.36 kJ/mol, respectively. The kinetic analysis showed that adding a catalyst did not change the decomposition mechanism. Co-pyrolysis of biomass and RSO could effectively improve the yield and selectivity of aromatics, when the pyrolysis temperature and catalytic temperature were 550 °C and 500 °C, respectively, the mass space velocity of RSO was 0.4 mL/min, the reaction time was 30min, the yields of benzene, toluene, xylene and ethyl benzene (BTXE) were up to 78.77%, and the selectivity of benzene, toluene and xylene was much better. Finally, the coke yield was substantially lower.     

Bio‐Based,Self‐Condensed Polyols

A new method for the synthesis of high‐molar‐mass (MM), bio‐based polyols for elastic polyurethanes is developed. This process is based on the self‐condensation of low MM polyols (M_n ≈ 1000) and vacuum removal of the resulting glycerol. Self‐condensation products are hyperbranched estolide polyols with average MMs close to 3000 and hydroxyl numbers in the range of 40–95 mg KOH g^?1. Three polyols, one with primary and two with secondary hydroxyls and different functionalities, are studied. The transesterification proceeded much faster with primary hydroxyls, leading to high‐viscosity products. The effect of functionality and reactivity of starting polyols on properties is discussed. Practical applications: The process is useful for upgrading the existing natural oil‐based polyols to higher MM, lower OH number and variable‐functionality polyols, for expanding application in the urethane field. The process is simple, involving just an oil‐based polyol, a catalyst, and heating under vacuum.     

露天矿边坡锚固参数地震响应敏感性分析

利用FLAC^3D软件建立了锚固露天矿边坡数值模型,研究了锚固参数对锚杆动力响应、边坡位移响应以及边坡塑性应变贯通长度的影响,并通过权重分析法对锚固参数进行了敏感性分析。研究结果表明:随着锚杆长度和锚孔直径增加,边坡永久水平位移和塑性应变区贯通率都减小,锚杆轴力峰值逐渐增大;随着锚杆竖向间距增大,三者均增大;随着锚固倾角增大,边坡永久水平位移和塑性应变区贯通率先减小后增大,锚杆轴力峰值则先增大后减小;锚固参数对锚杆轴力的影响权重由高到低依次为锚孔直径、锚杆长度、锚杆间距、锚固倾角;对塑性应变区贯通率影响权重由高到低依次为锚杆间距、锚孔直径、锚杆长度、锚固倾角;对边坡位移的影响权重由高到低依次为锚杆间距、锚杆长度、锚孔直径、锚固倾角。     

A油区清垢剂与缓蚀剂的优选分析

随着油田开发进程的深入,注水驱油早已成为最为常见的开采方式之一。实践表明,不论是从水体的配伍性还是经济性的角度来看,经过多重技术处理的采出污水都是回注水体的最佳选择。但是由于作业废水和废置液包含化学成分较多,常会因其间的相互反应而腐蚀堵塞管线等设备。因此,本文以A油区为例,基于其实际的生产状况,根据采出污水结垢趋势和腐蚀原因,进行清垢剂与缓蚀剂的优选,以期为实际生产提供一点理论参考。     

Margarine-Like Emulsions Prepared with Coconut and Palm Oils: Analysis of Microstructure and Freeze–Thaw Stability by Differential Scanning Calorimetry

The objective was to study the microstructure and freeze–thaw stability of margarine-like emulsions formulated with vegetable fats using differential scanning calorimetry. Emulsions were prepared with 20% w/w dispersed aqueous phase and a continuous lipid phase composed by coconut oil (CO) and/or palm oil (PO) plus polyglycerol polyricinoleate (PGPR) as emulsifier. Mean temperature (T_M) and crystallization enthalpy (ΔH_c) were obtained from the exothermic peaks corresponding to freezing of aqueous phase. Successive cooling–heating–cooling cycles were applied to analyze changes in the exothermic peak. The emulsion prepared with CO (without PO) and 1% w/w PGPR in lipid phase showed higher water droplets size (T_M = −44.8 ± 0.1 °C) and lower quantity of stabilized aqueous phase (ΔH_c = 28.9 ± 1.2 J g⁻¹) prior to application of temperature cycles, while coalescence and (presumably) water transfer processes occurred during the treatment. The use of 2% w/w PGPR was sufficient to accomplish full stabilization of aqueous phase (T_M = −45.9 ± 0.1 °C; ΔH_c = 42.6 ± 0.3 J g⁻¹) before and after the freeze–thaw treatment. The total or partial (50%) substitution of CO by PO in emulsions with 1% w/w PGPR also improved the stability of the system, exhibiting slight microstructural changes. This enhanced stability would be linked to reduced water droplets size because of more rapid crystallization of lipid phase and immobilization of aqueous phase after emulsion preparation. In conclusion, it is possible to obtain margarine-like emulsions prepared with CO and/or PO using relatively low emulsifier concentration and maintaining a desired microstructure after freeze-thawing if the percentage ratio of both fats is controlled.